Tsubasa is a middle school student who is one of the first students to be kind to Mikan. He has the Alice of manipulating shadows. He met Mikan when he saves her from bullies. They have a brother-sister relationship. He has a star shaped mark on the left of his face, which is actually a punishment mark and will put him under pain by the person who gave it to him, which was Rui Amane, who seems to like him. Tsubasa found out about Ruka and Natsume's crush on Mikan when he hugged Mikan and the younger boys glared at him, and enjoys teasing them about their feelings for Mikan. Since Natsume thinks that Mikan has a crush on Tsubasa, he makes it a point to be around them so nothing happens. In the epilogue, they get married. He is a double star.
Misaki is good friends with Tsubasa and loves to pick on him a lot. However she is in love with Tsubasa, even though she denied at first. She also belongs to the Special Ability class and is one of the most beautiful looking people there. She has the Doppelgänger Alice and is also a member of Watching Over Ruka group, and it somehow appears that Kitsuneme and Yome have innocent crushes on her.[8] When Tsubasa goes to save Mikan, he asks Misaki to be his girlfriend if he came back alive, and she states she thought they had already been going out. In the epilogue, they get married.
Megane is one of Tsubasa and Misaki's friends. He wears spectacles and he has an Alice of Spirit hopping. 'Megane' is presumably a nickname, since it means glasses/spectacles in Japanese. He can possess any thing from robots to oranges and vases. In the anime, it is said that he has a crush on Megumi during the Special Ability's role-playing game in the Alice Festival. He belongs to the Special Ability Class.
Yuri is very popular with the girls mainly because of her female pheromone Alice. This is a fact which embarrasses her, but she claims that she is straight. She first appeared in episode 19 of the anime, where she was supposed to act as the prince but later was replaced by Mikan, because of an incident of sticking gum/bomb stuck on her hands, body and foot. She is in the Somatic class.
Kaname is Tsubasa's best friend. He was a very lonely kid with few friends due to his condition. He possesses the Alice of placing souls into stuffed animals, thus causing them to come to life. He has poor health and his usage of his Alice affects his lifespan. Despite this, he still makes dolls, for it is his way of proving to himself that he can make people happy. And the dolls he made serve as 'evidences of his existence'. He is also the creator of Mr. Bear. He belongs to the Technical Class, and is currently a Double Star.
Nobara is a first year student in the Middle School Division and is in the Dangerous Ability class. She has the Ice Alice. When she first met Mikan, she thought of Mikan as a cute girl. In the Academy, she is always being hated because of her Ice Alice and thus people nicknaming her "The Snow Woman" or "Ice Princess". Mikan is the first one to approach her with kindness and warmth, leading her to admire Mikan very much. She shares a deep bond with Persona, despite his actions. After leaving the Academy, she marries Persona and they have a daughter.